What is
Biodiesel?
Biodiesel
is the name for a variety of ester-based oxygenated fuels made from vegetable
oils or animal fats. The concept of using vegetable oil as a fuel
dates back to 1895 when Dr. Rudolf Diesel developed the first diesel engine
to run on vegetable oil. Diesel demonstrated his engine at the World Exhibition
in Paris in 1900 using peanut oil as fuel.
Properties
of Biodiesel
Today’s
diesel engines require a clean-burning, stable fuel that performs well
under a variety of operating conditions. Biodiesel is the only alternative
fuel that can be used directly in any existing, unmodified diesel engine.
Because it has similar properties to petroleum diesel fuel, biodiesel can
be blended in any ratio with petroleum diesel fuel. Many federal and state
fleet vehicles in USA are already using biodiesel blends in their existing
diesel engines.
The
low emissions of biodiesel make it an ideal fuel for use in marine areas,
national parks and forests, and heavily polluted cities. Biodiesel has
many advantages as a transport fuel. For example, biodiesel can be produced
from domestically grown oilseed plants such as canola. Producing biodiesel
from domestic crops reduces the Australia's dependence on foreign petroleum,
increases agricultural revenue, and creates jobs.
Key
Advantages of Biodiesel:
1.
Biodiesel is the only alternative fuel in the US to complete EPA Tier I
Health Effects Testing under section 211(b) of the Clean Air Act, which
provide the most thorough inventory of environmental and human health effects
attributes that current technology will allow.
2.
Biodiesel is the only alternative fuel that runs in any conventional, unmodified
diesel engine. It can be stored anywhere that petroleum diesel fuel is
stored.
3.
Biodiesel can be used alone or mixed in any ratio with petroleum diesel
fuel. The most common blend is a mix of 20% biodiesel with 80% petroleum
diesel, or "B20."
4.
The lifecycle production and use of biodiesel produces approximately 80%
less carbon dioxide emissions, and almost 100% less sulphur dioxide. Combustion
of biodiesel alone provides over a 90% reduction in total unburned hydrocarbons,
and a 75-90% reduction in aromatic hydrocarbons. Biodiesel further provides
significant reductions in particulates and carbon monoxide than petroleum
diesel fuel. Biodiesel provides a slight increase or decrease in nitrogen
oxides depending on engine family and testing procedures. Based on Ames
Mutagenicity tests, biodiesel provides a 90% reduction in cancer risks.
5.
Biodiesel is 11% oxygen by weight and contains no sulphur. The use of biodiesel
can extend the life of diesel engines because it is more lubricating than
petroleum diesel fuel, while fuel consumption, auto ignition, power output,
and engine torque are relatively unaffected by biodiesel.
6.
Biodiesel is safe to handle and transport because it is as biodegradable
as sugar, 10 times less toxic than table salt, and has a high flashpoint
of about 125°C compared to petroleum diesel fuel, which has a flash
point of 55°C.
7.
Biodiesel can be made from domestically produced, renewable oilseed crops
such as soybeans, canola, cotton seed and mustard seed.
8.
Biodiesel is a proven fuel with over 30 million successful US road miles,
and over 20 years of use in Europe.
9.
When burned in a diesel engine, biodiesel replaces the exhaust odor of
petroleum diesel with the pleasant smell of popcorn or french fries.
10.
The Congressional Budget Office, and Department of Defense, US Department
of Agriculture, and others have determined that biodiesel is the low cost
alternative fuel option for fleets to meet requirements of the Energy Policy
Act.
Biodiesel
Impact
An
important factor that is not usually considered when calculating the costs
and benefits of industrial feedstock materials is the macroeconomic effect
associated with domestically produced, renewable energy sources. Economic
benefits of a biodiesel industry in the US would include value added to
the feedstock (oilseeds or animal fats), an increased number of manufacturing
jobs, an increased tax base from plant operations and income taxes, investments
in plant and equipment, improvement of our trade balance, and reductions
in health care costs due to improved air quality and greenhouse gas mitigation.
Biodiesel
has positive impacts on the state economy. An Iowa State University
study concluded that three economic benefits would accrue to state from
biodiesel. First, biodiesel expands demand for soybean oil, causing processors
to pay more for soybeans, In addition, soybean farmers near the biodiesel
plant would receive slightly higher prices for soybeans; and third, the
presence of a facility that creates energy from soybeans would add value
to the state's industrial and income base.
Dr.
Hayes concluded that, "If the state of Iowa were to mandate the use of
a 20 percent biodiesel blend in its state vehicle fleet where feasible,
the total additional cost of this policy would range from $400,000 to $500,000.
If it could be shown that this policy would result in a new five million
gallon biodiesel plant in the state, then the policy would create more
new tax revenues than it would cost and would clearly be in the best interest
of the state."
Biodiesel
has positive implications for production agriculture. A 1996 economic
study published by the USDA Office of Energy predicted that a modest, sustained
annual market for biodiesel of 100 million gallons in the US would contribute
approximately seven cents to the price of each bushel of soybeans produced
in the US. Based on last years harvested crop, the increase could have
resulted in more than $168 million directly to the use of biodiesel.
Biodiesel
has a positive impact on the US balance of trade. A 1998 biodiesel
lifecycle study jointly sponsored by the US Department of Energy and the
US Department of Agriculture concluded that increased use of biodiesel
and biodiesel blended fuels such as B20 would substantially benefit our
economy. The report concluded that national spending to import petroleum
sends significant amounts of dollars out of our domestic economy every
year. Biodiesel offers the potential to shift this spending from foreign
imports to domestically produced energy. The report notes: "With its ability
to be used directly in existing diesel engines, biodiesel offers the immediate
potential to reduce our demand for petroleum in the transportation sector."
Biodiesel
contributes jobs to the local economy. Economic work conducted at the
University of Missouri estimated the benefits of producing biodiesel in
a metropolitan region. This study concluded that 100 million gallons of
biodiesel production could generate an estimated $8.34 million increase
in personal income and over 6,000 additional temporary or permanent jobs
for the metropolitan region.
Biodiesel
Usage
Basic
Terminology: Biodiesel is the pure, or 100 percent, biodiesel fuel.
It
is referred to as B100 or "neat" fuel.
A
biodiesel
blend is pure biodiesel blended with petrodiesel. Biodiesel blends
are referred to as Bxx. The xx indicates the amount of biodiesel the blend
(i.e., a B20 blend is 20 percent biodiesel and 80 percent petrodiesel).
Ensure
the neat biodiesel fuel meets the biodiesel
specification for pure biodiesel before blending with petrodiesel.
The
specification for biodiesel is designed to ensure that consumers will not
experience operational problems from the fuel’s use. Make sure that biodiesel
meets this specification and that the fuel supplier will warrant this fact.
Quality fuel will provide the consumer with improved air quality and enhanced
operability. Poor quality fuel will create operability problems and increased
maintenance activity. Purchase only qualified fuel from a reputable source.
Check
fuel filters on the vehicles and in the delivery system frequently upon
initial biodiesel use and change them as necessary. Biodiesel
and biodiesel blends have excellent solvent properties. In some cases the
use of petrodiesel, especially #2 petrodiesel (has not been observed with
#1), leaves a deposit in the bottom of fueling lines, tanks, and delivery
systems over time. The use of biodiesel can dissolve this sediment and
result in the need to change filters more frequently when first using biodiesel
until the whole system has been cleaned of the deposits left by the petrodiesel.
This same phenomenon has been observed when switching from #2 to #1 petrodiesel.
Be
aware of biodiesel's freezing properties and take precautions as with #2
petrodiesel use in cold weather. A 20 percent blend of biodiesel
with petrodiesel raises the freezing properties approximately 3° to
5° F (pour point, cloud point, cold filter plugging point). In most
cases, this has not been an issue. Twenty percent biodiesel blends have
been used in the upper Wisconsin area and in Iowa during -25° F weather
with no problems. Solutions to biodiesel winter operability problems are
the same solutions used with conventional #2 petrodiesel (use a pour point
depressant, blend with #1diesel, use engine block or fuel filter heaters
on the engine, store the vehicles near or in a building, etc.). Neat biodiesel
will begin to freeze at about 25° F and, if used or stored on site,
will need to be kept in an area that will not get below that temperature.
Most underground tanks are around 50° F and are not a problem.
Wipe
painted surfaces immediately when using biodiesel. As mentioned earlier,
biodiesel is a good solvent. Biodiesel can, if left on a painted surface
long enough, dissolve certain types of paints. Therefore it is recommended
to wipe any biodiesel or biodiesel blend spills from painted surfaces immediately.
Store
biodiesel or biodiesel blend soaked rags in a safety can to avoid spontaneous
combustion. Biodiesel soaked rags should be stored in a safety
can or dried individually to avoid the potential for spontaneous combustion.
Biodiesel is made from vegetable oils and animal fats which can oxidize
and degrade over time. The oxidizing process can produce heat. In certain
environments, for example, a pile of oil soaked rags can become concentrated
enough to result in a spontaneous fire. (Note: Paul has a hole in seat
of his van to testify to this!!!)
Use
the biodiesel within one year. All fuels, including #2 and #1
petrodiesel, have a shelf life. This is also true with biodiesel and biodiesel
blends. Industry experts recommend that biodiesel be used within one year
to ensure that the quality of the fuel is maintained. Storage time does
not impact biodiesel distribution given biodiesel’s production logistics.
Biodiesel is generally not stored for long periods of time. Production
levels and rates are established to meet demand (similar to "just in time"
inventory methods). This is an advantage enjoyed by renewable fuels, like
biodiesel, that cannot be shared by its fossil fuel counterparts.
The
Biodiesel Association of Australia is available to answer additional questions
regarding the transition to biodiesel fuel use. Please do not hesitate
to call and ask your questions.
Emissions
Biodiesel
is the first and only alternative fuel to have a complete evaluation of
emission results and potential health effects submitted to the U.S. Environmental
Protection Agency (EPA) under the Clean Air Act Section 211(b). These programs
include the most stringent emissions testing protocols ever required by
EPA for certification of fuels or fuel additives in the US. The data gathered
through these tests complete the most thorough inventory of the environmental
and human health effects attributes that current technology will allow.
A survey of the results is provided in the table below.
|
BIODIESEL
EMISSIONS COMPARED TO CONVENTIONAL DIESEL
|
| Emission
Type |
B100
|
B20
|
| Regulated |
|
|
| Total
Unburned Hydrocarbons |
-93%
|
-30%
|
| Carbon
Monoxide |
-50%
|
-20%
|
| Particulate
Matter |
-30%
|
-22%
|
| NOx |
+13%
|
+2%
|
| |
|
|
| Non-Regulated |
|
|
| |
|
|
| Sulfates |
-100%
|
-20%*
|
| PAH
(Polycyclic Aromatic Hydrocarbons)** |
-80%
|
-13%
|
| nPAH
(nitrated PAH’s)** |
-90%
|
-50%***
|
| Ozone
potential of speciated HC |
-50%
|
-10%
|
| *
Estimated from B100 result |
|
|
| **
Average reduction across all compounds measured |
|
|
| ***
2-nitroflourine results were within test method variability |
|
|
The
overall ozone (smog) forming potential of biodiesel is less than diesel
fuel. The ozone forming potential of the speciated hydrocarbon emissions
was nearly 50 percent less than that measured for diesel fuel.
Sulphur
emissions are essentially eliminated with pure biodiesel. The exhaust
emissions of sulphur oxides and sulfates (major components of acid rain)
from biodiesel were essentially eliminated compared to sulphur oxides and
sulphates from diesel.
Criteria
pollutants are reduced with biodiesel use. The use of biodiesel in
an unmodified Cummins N14 diesel engine resulted in substantial reductions
of unburned hydrocarbons, carbon monoxide, and particulate matter. Emissions
of nitrogen oxides were slightly increased.
Carbon
Monoxide -- The exhaust emissions of carbon monoxide (a poisonous gas)
from biodiesel were 50 percent lower than carbon monoxide emissions from
diesel.
Particulate
Matter -- Breathing particulate has been shown to be a human health
hazard. The exhaust emissions of particulate matter from biodiesel were
30 percent lower than overall particulate matter emissions from diesel.
Hydrocarbons
-- The exhaust emissions of total hydrocarbons (a contributing factor in
the localized formation of smog and ozone) were 93 percent lower for biodiesel
than diesel fuel.
Nitrogen
Oxides -- NOx emissions from biodiesel increase or decrease depending
on the engine family and testing procedures. NOx emissions (a contributing
factor in the localized formation of smog and ozone) from pure (100%) biodiesel
increased in this test by 13 percent. However, biodiesel’s lack of sulphur
allows the use of NOx control technologies that cannot be used with conventional
diesel. So, biodiesel NOx emissions can be effectively managed and efficiently
eliminated as a concern of the fuel’s use.
Biodiesel
reduces the health risks associated with petroleum diesel. Biodiesel
emissions showed decreased levels of PAH and nitrited PAH compounds which
have been identified as potential cancer causing compounds. In the recent
testing, PAH compounds were reduced by 75 to 85 percent, with the exception
of benzo(a)anthracene, which was reduced by roughly 50 percent. Targeted
nPAH compounds were also reduced dramatically with biodiesel fuel, with
2-nitrofluorene and 1-nitropyrene reduced by 90 percent, and the rest of
the nPAH compounds reduced to only trace levels.
Environmental
& Safety Information
| Acute
Oral Toxicity/Rates |
Biodiesel
is nontoxic. The acute oral LD50 (lethal dose) is greater than 17.4 g/Kg
body weight. By comparison, table salt (NaCL) is nearly 10 times more toxic. |
| Skin
Irritation -Humans |
A
24-hr. human patch test indicated that undiluted biodiesel produced very
mild irritation. The irritation was less than the result produced by a
4 percent soap and water solution. |
| Aquatic
Toxicity |
A
96-hr. lethal concentration for bluegill of biodiesel grade methyl esters
was greater than 1000 mg/L. Lethal concentrations at these levels are generally
deemed "insignificant" according to NIOSH (National Institute for Occupational
Safety and Health) guidelines in its Registry of the Toxic Effects of
Chemical Substances. |
| Biodegradability |
Biodiesel
degrades about four times faster than petroleum diesel. Within 28 days,
pure biodiesel degrades 85 to 88 percent in water. Dextrose (a test sugar
used as the positive control when testing biodegradability) degraded at
the same rate. Blending biodiesel with diesel fuel accelerates its biodegradability.
For example, blends of 20 percent biodiesel and 80 percent diesel fuel
degrade twice as fast as #2 diesel alone. |
| Flash
Point |
The
flash point of a fuel is defined as the temperature at which it will ignite
when exposed to a spark or flame. Biodiesel’s flash point is over 125°
Celsius, well above petroleum based diesel fuel’s flash point of around
58° Celsius. Testing has shown the flash point of biodiesel blends
increases as the percentage of biodiesel increases. Therefore, biodiesel
and blends of biodiesel with petroleum diesel are safer to store, handle,
and use than conventional diesel fuel. |
Fuel
Displacement
Vehicles
that operate on 20 percent blends of biodiesel blended with 80 percent
conventional diesel (B20) will, on average, displace more than twice as
much petroleum as conventional light-duty passenger vehicles already covered
under the Energy Policy Act (EPACT).
Diesel
engines used by medium and heavy duty government fleets consume significantly
greater quantities of fuel than the light duty passenger vehicles that
comprise the majority of the current EPACT fleets. The diesel engine vehicle
portion of these fleets will be the primary market for B20.
The
chart below illustrates the displacement potential of B20. All of the figures
on vehicle miles travelled, miles per gallon, and total fuel usage are
provided by the US Department of Energy’s Energy Information Administration
publication: Alternatives to Traditional Transportation Fuels.
| Vehicle/Fleet
Type |
VMT
|
MPG
|
Total
Fuel Use
|
Percent
(%) Petroleum Displaced by Alt. Fuel
|
Total
Gallons Petroleum Displaced by Alt. Fuel
|
| Light-Duty
Passenger Vehicle (E85) |
8000
|
24
|
334
Gal.
|
85%
|
283
Gal.
|
| Light-Duty
Truck (B20) |
16400
|
16
|
1025
Gal.
|
20%
|
205
Gal.
|
| Medium-Duty
Truck (B20) |
16400
|
8
|
2050
Gal.
|
20%
|
410
Gal.
|
| Heavy-Duty
Truck (B20) |
16400
|
6
|
2734
Gal.
|
20%
|
547
Gal.
|
| School
Bus (B20) |
8000
|
8
|
1000
Gal.
|
20%
|
200
Gal.
|
| Transit
Bus (B20) |
33200
|
4
|
8300
Gal.
|
20%
|
1660
Gal.
|
VMT
= Vehicle Miles Traveled MPG = Miles Per Gallon
As
the chart shows, the key to total displacement is not the percentage blend
level of the fuel, rather it is a function of the fuel blend level, fuel
economy of the vehicles and the annual use of that vehicle by the fleet.
On
average, B20 vehicles will displace more petroleum than existing light-duty
EPACT passenger vehicles operating on higher blend levels because medium
and heavy duty diesel engine vehicles consume substantially greater volumes
of fuel than light-duty passenger vehicles.
Performance
Successful
alternative fuels fulfil environmental and energy security needs without
sacrificing operating performance. Operationally, biodiesel performs very
similar to low sulphur diesel in terms of power, torque, and fuel without
major modification of engines or infrastructure.
Biodiesel
offers similar power to diesel fuel. One of the major advantages of
biodiesel is the fact that it can be used in existing engines and fuel
injection equipment with little impact to operating performance. Biodiesel
has a higher cetane number than U.S. diesel fuel. In over 15 million miles
of in-field demonstrations biodiesel showed similar fuel consumption, horsepower,
torque, and haulage rates as conventional diesel fuel.
Biodiesel
provides significant lubricity improvement over petroleum diesel fuel.
Lubricity results of biodiesel and petroleum diesel using industry test
methods indicate that there is a marked improvement in lubricity when biodiesel
is added to conventional diesel fuel. Even biodiesel levels below 1 percent
can provide up to a 30 percent increase in lubricity.
Compatibility
of biodiesel with engine components. In general, biodiesel will soften
and degrade certain types of elastomers and natural rubber compounds over
time. Using high percent blends can impact fuel system components (primarily
fuel hoses and fuel pump seals), that contain elastomer compounds incompatible
with biodiesel. Manufacturers recommend that natural or butyl rubbers not
be allowed to come in contact with pure biodiesel. Biodiesel will lead
to degradation of these materials over time, although the effect is lessened
with biodiesel blends. If a fuel system does contain these materials and
user’s wish to fuel with pure biodiesel, replacement with compatible elastomers
is recommended. The recent switch to low sulphur diesel fuel has caused
many OEMs to switch to components suitable for use with biodiesel, but
users should contact their OEM for specific information.
Biodiesel
in cold weather. Cold weather can cloud and even gel any diesel fuel,
including biodiesel. Users of a 20 percent biodiesel blend will experience
a decrease of the cold flow properties (cold filter plugging point, cloud
point, pour point) of approximately 3 to 5° Fahrenheit. Precautions
beyond those already employed for petroleum diesel are not needed for fueling
with 20 percent blends. However, neat (100 percent) biodiesel will gell
faster than petrodiesel in cold weather operations. Solutions for winter
operability with biodiesel are much the same as that for low-sulphur #2
diesel (i.e., blending with #1 diesel, utilization of fuel heaters, and
storage of the vehicle in or near a building).
Production
The
production of biodiesel, or alkyl esters, is well known. There are three
basic routes to ester production from oils and fats:
-
Base catalyzed
transesterification of the oil with alcohol.
-
Direct
acid catalyzed esterification of the oil with methanol.
-
Conversion
of the oil to fatty acids, and then to Alkyl esters with acid catalysis.
The majority
of the alkyl esters produced today are done with the base catalyzed reaction
because it is the most economic for several reasons:
-
Low temperature
(150 F) and pressure (20 psi) processing.
-
High conversion
(98%) with minimal side reactions and reaction time.
-
Direct
conversion to methyl ester with no intermediate steps.
-
Exotic
materials of construction are not necessary.
The general
process is depicted below. A fat or oil is reacted with an alcohol, like
methanol, in the presence of a catalyst to produce glycerine and methyl
esters or biodiesel. The methanol is charged in excess to assist in quick
conversion and recovered for reuse. The catalyst is usually sodium or potassium
hydroxide which has already been mixed with the methanol.
Questions
Click
this link for a list of frequently asked questions about Biodiesel!
Who can
answer my questions about biodiesel?
The Biodiesel
Association of Australia is developing a library of information on Biodiesel
in the US, Europe and Australia. The library will consist of source material
and links to relevant information. The library is made available to members
of the Association.
Members
also have both post and read access to the Biodiesel Information Forum.
This will broaden the base from which you can seek both theoretical and
practical information about biodiesel manufacture and use.
Members
also have access to the "Member Locator" which enables you to access contact
details for members within a self specified radius of a specific postcode.
Because we respect the privacy of our members, this feature is only available
to BAA members, and only includes those members who have indicated that
they are prepared to be contacted by other BAA members.
This
gives members access to the trials, tribulations and experiences of other
members.
As
a member, you are free to call us on (02) 9803 0096 02 (02) 9764 7617 with
your information request. Non-members have full access to all the public
documentation and are also free to call for information - However priority
is given to members.
Specification
for Biodiesel (B100)
Look
at our standards
section for the current information on the status of the biodiesel
standards in Australia.
Sample
Material Safety Data Sheet
1.
CHEMICAL
PRODUCT
General
Product Name: Biodiesel
Synonyms:
Methyl Soyate, Rapeseed Methyl Ester (RME), Methyl Tallowate
Product
Description: Methyl esters from lipid sources
CAS
Number: 67784-80-9
2.
COMPOSITION/INFORMATION ON INGREDIENTS
This
product contains no hazardous materials.
3.
HAZARDS IDENTIFICATION
Potential
Health Effects:
INHALATION:
Negligible
unless heated to produce vapors. Vapors or finely misted materials may
irritate the mucous membranes and cause irritation, dizziness, and nausea.
Remove to fresh air.
EYE
CONTACT:
May
cause irritation. Irrigate eye with water for at least 15 to 20 minutes.
Seek medical attention if symptoms persist.
SKIN
CONTACT:
Prolonged
or repeated contact is not likely to cause significant skin irritation.
Material is sometimes encountered at elevated temperatures. Thermal burns
are possible.
INGESTION:
No
hazards anticipated from ingestion incidental to industrial exposure.
4.
FIRST AID MEASURES
EYES:
Irrigate
eyes with a heavy stream of water for at least 15 to 20 minutes.
SKIN:
Wash
exposed areas of the body with soap and water.
INHALATION:
Remove
from area of exposure, seek medical attention if symptoms persist.
INGESTION:
Give
one or two glasses of water to drink. If gastro-intestinal symptoms develop,
consult medical personnel. (Never give anything by mouth to an unconscious
person.)
5.
FIRE FIGHTING MEASURES
Flash
Point (Method Used): 100.0° C min (ASTM 93)
Flammability
Limits: None known
EXTINGUISHING
MEDIA:
Dry
chemical, foam, halon, CO2 , water spray (fog). Water stream may splash
the burning liquid and spread fire.
SPECIAL
FIRE FIGHTING PROCEDURES:
Use
water spray to cool drums exposed to fire.
UNUSUAL
FIRE AND EXPLOSION HAZARDS:
Oil
soaked rags can cause spontaneous combustion if not handled properly. Before
disposal, wash rags with soap and water and dry in well ventilated area.
Firefighters should use self-contained breathing apparatus to avoid exposure
to smoke and vapor.
6.ACCIDENTAL
RELEASE MEASURES SPILL CLEAN-UP PROCEDURES
Remove
sources of ignition, contain spill to smallest area possible. Stop leak
if possible. Pick up small spills with absorbent materials such as paper
towels, "Oil Dry", sand or dirt. Recover large spills for salvage or disposal.
Wash hard surfaces with safety solvent or detergent to remove remaining
oil film. Greasy nature will result in a slippery surface.
7.
HANDLING AND STORAGE
Store
in closed containers between 50° F and 120° F.
Keep
away from oxidizing agents, excessive heat, and ignition sources.
Store
and use in well ventilated areas.
Do
not store or use near heat, spark, or flame, store out of sun.
Do
not puncture, drag, or slide this container.
Drum
is not a pressure vessel; never use pressure to empty.
8.
EXPOSURE CONTROL /PERSONAL PROTECTION
RESPIRATORY
PROTECTION:
If
vapours or mists are generated, wear a NIOSH approved organic vapor/mist
respirator.
PROTECTIVE
CLOTHING:
Safety
glasses, goggles, or face shield recommended to protect eyes from mists
or splashing. PVC coated gloves recommended to prevent skin contact.
OTHER
PROTECTIVE MEASURES:
Employees
must practice good personal hygiene, washing exposed areas of skin several
times daily and laundering contaminated clothing before re-use.
9.
PHYSICAL AND CHEMICAL PROPERTIES
Boiling
Point, 760 mm Hg:>200°C
Volatiles, % by Volume: <2
Specific
Gravity (H2 O=1): 0.88
Solubility in H2 O, % by Volume: insoluble
Vapour
Pressure, mm Hg: <2
Evaporation Rate, Butyl Acetate=1: <1
Vapour
Density, Air=1:>1
Appearance
and Odour: pale yellow liquid, mild odour
10.
STABILITY AND REACTIVITY
GENERAL:
This
product is stable and hazardous polymerisation will not occur.
INCOMPATIBLE
MATERIALS AND CONDITIONS TO AVOID:
Strong
oxidizing agents
HAZARDOUS
DECOMPOSITION PRODUCTS:
Combustion
produces carbon monoxide, carbon dioxide along with thick smoke.
11.
DISPOSAL CONSIDERATIONS
WASTE
DISPOSAL:
Waste
may be disposed of by a licensed waste disposal company. Contaminated absorbent
material may be disposed of in an approved landfill. Follow local, state
and federal disposal regulations.
12.
TRANSPORT INFORMATION
UN
HAZARD CLASS: N/A
NMFC
(National Motor Freight Classification):
PROPER
SHIPPING NAME: Fatty acid ester
IDENTIFICATION
NUMBER: 144920
SHIPPING
CLASSIFICATION: 65
13.
REGULATORY INFORMATION
OSHA
STATUS:
This
product is not hazardous under the criteria of the Federal OSHA Hazard
Communication Standard 29 CFR 1910.1200. However, thermal processing and
decomposition fumes from this product may be hazardous as noted in Sections
2 and 3.
TSCA
STATUS:
This
product is listed on TSCA.
CERCLA
(Comprehensive Response Compensation and Liability Act):
NOT
reportable.
SARA
TITLE III (Superfund Amendments and Reauthorisation Act):
Section
312 Extremely Hazardous Substances:
None
Section
311/312 Hazard Categories:
Non-hazardous
under Section 311/312
Section
313 Toxic Chemicals:
None
RCRA
STATUS:
If
discarded in its purchased form, this product would not be a hazardous
waste either by listing or by characteristic. However, under RCRA, it is
the responsibility of the product user to determine at the time of disposal,
whether a material containing the product or derived from the product should
be classified as a hazardous waste, (40 CFR 261.20-24)
CALIFORNIA
PROPOSITION 65:
The
following statement is made in order to comply with the California Safe
Drinking Water and Toxic Enforcement Act of 1986. This product contains
no chemicals known to the state of California to cause cancer.
14.
OTHER INFORMATION
This
information relates only to the specific material designated and may not
be valid for such material used in combination with any other materials
or in any other process. Such information is to the best of the company’s
knowledge and believed accurate and reliable as of the date indicated.
However, no representation, warranty or guarantee of any kind, express
or implied, is made as to its accuracy, reliability or completeness and
we assume no responsibility for any loss, damage or expense, direct or
consequential, arising out of use. It is the user’s responsibility to satisfy
himself as to the suitableness and completeness of such information for
his own particular use.
Biodiesel
2000
Indicators
that the Biodiesel Industry is Growing and Poised to be a Significant Contributor
to the U.S. Alternative Fuels Market
Recent
achievement of three major long-term objectives. Because of the following
3 long-term achievements, biodiesel has become one of the fastest (if not
the fastest) growing alternative fuels in the country.
-
Health
Effects: In May 2000, biodiesel became the only alternative fuel in
the country to have successfully completed the EPA’s Tier I and Tier
II Health Effects testing under Section 211(b) of the Clean Air Act. The
Tier I testing conclusively demonstrated biodiesel’s significant reductions
in most currently regulated emissions as well as most unregulated emissions—especially
those associated with cancer and lung disease. Tier II testing demonstrated
biodiesel’s non-toxic effect on health.
-
EPACT:
Effective November 1998, B20, a blend of 20% biodiesel and 80% petroleum
diesel, was approved by Congress as an EPAct (Energy Policy Act of 1992)
compliance strategy. The legislation allowed EPAct fleets to meet their
alternative fuel vehicle purchase requirements simply by buying 450 gallons
of pure biodiesel and burning it in new or existing diesel vehicles in
at least a 20% blend with diesel fuel. The Congressional Budget Office
and the Department of Defence have confirmed that the biodiesel option
is the lowest cost alternative fuel option for meeting the Federal Government’s
EPACT compliance requirements.
-
ASTM:
In December 1998, the American Society of Testing and Materials (ASTM)
issued a provisional specification (PS 121) for biodiesel fuel. ASTM is
the premier standard-setting organization for fuels and additives in the
U.S. The EPA has adopted the ASTM standard and state divisions of weights
and measures currently are considering its adoption. This development was
crucial in standardizing fuel quality for biodiesel in the U.S. market.
Current
Industry Progress and Initiatives:
Biodiesel
Use Is Increasing Significantly. In March 1999, three major fleets
were known to be using B20 for EPAct compliance. By October 1999, that
number had increased to over 25 and includes such fleets as the Ohio Department
of Transportation, U.S. Postal Service, General Services Administration,
Alabama Power and the U.S. Department of Agriculture. That is more than
a 700% increase in biodiesel users in six months. New fleets are committing
every day.
Low
Blend Premium Diesel Development: Since 1997, seven companies have
released premium additive packages containing biodiesel in which biodiesel
is a major marketing aspect of the product. In the summer of 1999, Koch—the
second largest privately owned company in the US behind Cargill-launched
a new premium diesel fuel product, US SoyField Diesel, which is now in
more than 20 terminals in the Midwest and expanding. Also in 1999, Country
Energy (the Farmland/Cenex petroleum joint venture) launched SoyMaster,
its proprietary premium diesel containing biodiesel, in four terminals
in the Midwest. These petroleum companies, and others are evaluating the
expansion of their product lines to include B20 and market the alternative
fuel to their network of customers through their terminal and distributor
systems.
Biodiesel
Supplier Base is Increasing: In 1996 there were two companies who were
registered biodiesel suppliers. In 1999 there are 13 companies who have
invested millions of private dollars into the development of the biodiesel
manufacturing plants and industry development activities. In fact, a new,
less expensive continuous biodiesel process was patented last summer with
plans to build several additional plants around the country. The number
of inquiries received by NBB staff and consultants for biodiesel manufacturing
plants has skyrocketed over the last 12 months.
Political
and Public Support is Increasing Significantly: Over the last 12 months,
there has been a significant amount of increased political support for
biodiesel. Biodiesel has been hampered compared to other alternative fuels,
because public policies were not in place to allow the quantification of
the significant energy security, agricultural, and environmental benefits
of the fuel. Biodiesel is now being included in major state and nation-wide
legislative efforts, which are providing a mechanism to quantify the benefits
of the fuel and are making it a cost-competitive option for achieving many
of the nation and state-wide goals. Major biodiesel initiatives have recently
passed in Arizona, Ohio, New Jersey, Delaware, and Iowa. Bipartisan
federal Legislation was introduced in May 2000 by Senator’s Daschle and
Lugar which would require a percentage of biodiesel in all low-sulphur
diesel fuel as a renewable lubricity additive. And environmentalists
have finally begun to recognize the environmental benefits of the fuel-
biodiesel was used to power Earth Day 2000.
Presidential
Executive Orders: On August 12, 1999, President Clinton signed Executive
Order 13134, Developing and Promoting Biobased Products and Bioenergy,
which calls for the expanded use of bio-based fuels such as biodiesel.
Furthermore, on September 14, 1998, the President signed Executive Order
13101, Greening the Government Through Waste Prevention, Recycling, and
Federal Acquisition, which gives preference to bio-based products for federal
government procurement. Finally, on April 22, the president signed Executive
Order 13149 which increases the governments targets for displacing petroleum.
Military:
The National Biodiesel Board just entered into a Cooperative Research and
Development Agreement (CRADA) with the Tank, Automotive and Armament Command
(TAACOM) of the U.S. Army to assist them in their effort to incorporate
biodiesel into the procurement provisions for the military.
The
Defense Logistics Agency (DLA) is streamlining the biodiesel procurement
process for both the military and individual federal agencies.
The
Department of Defense has issued guidance to all branches of the military
for biodiesel use that is favorable to the purchase of the fuel.
Biodiesel
blends have been included in the 21st Century Truck Initiative,
being spearheaded by TACOM and the National Automotive Center as a leading
alternative fuel for heavy-duty trucks because other alternatives to fossil
fuels are not able to deliver the power and performance demanded by the
heavy-duty sector.
OEMs:
Ford and Chrysler have begun biodiesel research initiatives, with Ford’s
efforts being the most advanced. Ford is conducting independent compatibility
testing in anticipation of providing diesel engines certified to operate
on biodiesel. Chrysler has included biodiesel in its compatibility specifications.
Most major diesel engine manufacturers have affirmed that use of B20 in
their equipment will not void their warranty and are actively working with
industry on research and development activities. Moreover, the Fuel Injection
Equipment manufacturers have issued letters recognizing biodiesel’s significant
role as a renewable lubricity additive.
Future
Market Dynamics Show Promise: Increasing pressure is being put on the
petroleum industry to reduce sulphur levels and increase cetane number
in diesel fuel. EPA and other air quality groups continue to increase pressure
to reduce the amount of compounds in diesel exhaust which have the potential
to cause cancer and lung disease. Furthermore, global warming and green
house gases will continue to gain attention. Biodiesel provides benefits
in all these areas, which will further increase the fuel’s economic competitiveness.
Moreover, biodiesel offers fleet managers an immediate and “seamless” ability
to transform their entire diesel fleet into a cleaner burning alternative
fuel fleet, without any capital investment.
Health
Effects Testing
HISTORY
In
June 2000, representatives of the U.S. Congress announced that biodiesel
had become the first and only alternative fuel to have successfully completed
the Tier I and Tier II Health Effects testing requirements of the Clean
Air Act Amendments of 1990. The soybean industry invested more than
two million dollars and four years into the health effects testing program
with the goal of setting biodiesel apart from other alternative fuels and
increasing consumer confidence in biodiesel.
TESTING
The
first tier of health effects testing was conducted by Southwest Research
Institute and involved a detailed analysis of biodiesel emissions.
Tier II was conducted by Lovelace Respiratory Research Institute, where
a 90-day sub-chronic inhalation study of biodiesel exhaust with specific
health assessments was completed.
RESULTS
Results
of the health effects testing concluded that biodiesel is non-toxic and
biodegradable, posing no threat to human health. Also among the findings
of biodiesel emissions compared to petroleum diesel emissions:
The
overall ozone (smog) forming potential of exhaust emissions from biodiesel
is 50% less.
The
exhaust emissions of carbon monoxide (a poisonous gas and a contributing
factor in the localized formation of smog and ozone) from biodiesel are
50% lower.
The
exhaust emissions of particulate matter (recognized as a contributing factor
in the respiratory disease) from biodiesel are 30% lower.
The
exhaust emissions of sulphur oxides and sulphates (major components of
acid rain) from biodiesel are complete eliminated.
The
exhaust emissions of hydrocarbons (a contributing factor in the localized
formation of smog and ozone) are 95% lower.
The
exhaust emissions for aromatic compounds known as PAH and NPAH compounds
(suspected of causing cancer) are substantially reduced for biodiesel compared
to diesel. Most PAH compounds were reduced by 75% to 85%. All
NPAH compounds were reduced by at least 90%.
SIGNIFICANCE
The
health effects testing results provide conclusive scientific evidence using
the most sophisticated technology available to validate the existing body
of testing data. The comprehensive body of biodiesel data serves
to demonstrate the significant benefits of biodiesel to the environment
and to public health. This will lead to increase consumer confidence
and increased use of biodiesel. Since the majority of biodiesel is
made from soybean oil, a promising new market is materializing for soybeans.
National
Impacts from Increased Biodiesel Usage
A
1998 biodiesel lifeyclcle study jointly sponsored by the U.S. Department
of Energy and the U.S. Department of Agriculture concluded that increased
use of biodiesel would benefit our national economy. Increased biodiesel
production would also result in significant economic benefits to state
economies as well as agricultural producers.
According
to economic modeling conducted by the Food and Agricultural Policy Research
Institute, (FAPRI), 70 million gallons of annual demand for biodiesel could
add $0.10 to $0.18 per bushel to the price of soybeans.
An
analysis conducted by the USDA Economic Economic Research Service estimates
that 100 million gallons of biodiesel demand would increase soybean oil
prices by 14%.
USDA
forecasts that ending stocks of soybean oil in 2000-01 will be 1.85 billion
pounds. Soybean meal demand is forecasted to increase more than soybean
oil demand.
Oilseed
industry experts estimate an additional four billion gallons of biodiesel
feedstock supply could be available through expanded soybean acreage, increased
utilization of oilseed crops and higher oil soybeans.
Under
current economic conditions, increased in soybean prices will result in
decreased federal outlays under the soybean marketing loan program.
The
utilization of biodiesel could have immediate impacts on the economy that
would increase increased farm income, increased economic activity and corresponding
increases to the local tax base, utilization of surplus soybean oil, and
decreased federal outlays under the soybean marketing loan program.
However, the biodiesel industry is currently not eligible for policy incentives
enjoyed by other segments of the fuels market that would increase biodiesel
sales and further market development.
Until
the early 1970's, the US was self sufficient in crude oil production.
However, imports of crude have been increasing at an accelerating rate
due to decreasing domestic production and increasing energy needs.
Petroleum imports now account for more than half of our total usage, and
make up the single largest component of our trade deficit.
A 2000
GAO report documented specific petroleum tax incentives that range from
about $330 million for the expensing of tertiary injectants (1980-2000)
to about $82 billion for certain cost depletion deductions (1968-2000).
The same
GAO report indicated that ethanol fuel tax incentives ranged from $198
million for alcohol fuel tax credits (1980-2000) to about $11 billion for
the excise tax exemption for alcohol fuels (1979-2000).
Although
the tax incentives provided to the ethanol industry are a fraction of those
provided to the petroleum industry, ethanol's favourable tax treatment
has been critical in the development of ethanol into a two billion gallon
per year industry. To date, the biodiesel industry has never received
any favorable tax or subsidy treatment, and is at a significant disadvantage
relative to petroleum. In fact, the US Congress is currently considering
legislation that would provide further incentives to domestically produced
petroleum, but would not apply to domestically produced biodiesel.
Inclusion of biodiesel into a comprehensive energy policy that promotes
domestically produced renewable fuels could have a significant impact on
the development of the biodiesel market, at a relatively low cost to US
consumers or taxpayers.
Policy
options such as a national renewable standard for diesel fuel would provide
significant benefits to the economy. In May 2000, EPA proposed a
limit on sulphur of 15 ppm maximum for on-highway diesel fuel by 2007.
This is a reduction of over 95% from the current limit of 500 ppm.
Removing the sulphur from diesel fuel will reduce fuel lubricity, harming
engine life. Biodiesel improves lubricity at very low percentages.
Biodiesel could be included as a low level blending component in diesel
fuel as a means to improve fuel lubricity while meeting other policy objectives.
The Energy Information Administration reports that the total US distillate
market in 1998 was over 55 billion gallons and 'on-highway' represented
the largest component of this use at over 30 billion gallons.
Inclusion
of biodiesel in on-road diesel fuel at a level of 1% for lubricity purposes
would result in the following:
-
300 million
gallons of biodiesel demand.
-
Utilization
of the oil from more than 214 million bushels of soybeans (over 2.2 billion
pounds of soybean oil).
-
Add a
minimum of 30¢ to the value of a bushel of soybeans, based
on economic analyses conducted by USDA-ERS and FAPRI.
-
Add more
than $800 million to gross farm income and decrease federal outlays under
the soybean marketing loan program in similar amounts.
-
Potentially
reduce fleet operating costs through increased equipment life.
The biodiesel
industry is currently reviewing policy options such as tax incentives,
relief of EPACT credit restrictions, as well as the inclusion of biodiesel
in the national diesel fuel pool that would further the development of
the biodiesel market, level the playing field in the alternative fuels
marketplace, and lead to national economic benefits.
Economic
activity from an activity from an industry can be categorized into direct,
indirect, and induced impacts. Direct impacts are those changes in
output or income that can be directly attributed to the industry.
Secondary impacts (indirect and induced) result from subsequent rounds
of spending and re-spending by consumers and businesses. The National
Biodiesel Board will conduct a macroeconomic study in spring 2001 to quantify
direct and secondary economic impacts, employment, balance of trade, and
increased level of economic activity and corresponding state and local
tax revenue that result from increased biodiesel usage.
Utah Biodiesel Cooperative - Copyright 2005
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